Start With A Compel

Start the game off with a Compel. Heck, start every single scene with a Compel. It has a number of good effects. From a purely mechanical viewpoint, it gives the whole Fate Point economy a bit of a kick-start. It'll familiarize you a bit more with the characters' Aspects. Because the players have picked Aspects they want in play, it automatically gives you something that they and their characters will be interested in. Seriously, give it a try.